TEL: +86-632-3671188
FAX:+86-632-3671189
E-mail:export@krchemical.com
ADD:No.1, Fuqian South Road, Xuecheng Chemical Industrial Park, Xuecheng District, Zaozhuang City, Shandong Province, China
1. Corrosion Challenges Facing Industrial Equipment
Metal equipment in industrial water systems faces multiple corrosion threats, including oxygen corrosion, electrochemical corrosion, and acid corrosion. These corrosion processes not only shorten equipment lifespan but may also trigger safety incidents such as leaks. Particularly in circulating water systems, corrosion issues become more pronounced due to continuous water evaporation and concentration, which increases the concentration of corrosive substances.
Traditional corrosion inhibitors often suffer from high usage concentrations and poor environmental adaptability. The development and application of novel corrosion inhibitors offer superior solutions to these challenges.
2. Mechanism of PBTCA Corrosion Inhibition
PBTCA achieves corrosion inhibition primarily through two mechanisms: First, a film-forming mechanism: its active groups bond with metal surfaces to create a dense protective film, blocking contact between corrosive media and the metal. Second, a polarization mechanism: it alters the electrochemical properties of the metal surface to inhibit corrosion currents.
Compared to other corrosion inhibitors, the protective film formed by PBTCA is thinner yet denser. This property ensures it does not impair heat transfer efficiency while providing long-lasting protection, making it particularly suitable for safeguarding heat exchange equipment.
3. Corrosion Protection Performance on Different Metals
PBTCA demonstrates excellent corrosion inhibition across various common industrial metals. For carbon steel equipment, it effectively suppresses uniform corrosion and pitting corrosion. For copper alloys, it prevents dezincification corrosion. For stainless steel, it mitigates the risk of stress corrosion cracking.
In practical applications, PBTCA's corrosion inhibition performance may vary across different metals. It is generally recommended to select an appropriate compound formulation based on the primary metal composition of the system. For example, a combination of PBTCA and azole compounds can be used for carbon steel-copper systems.
4. Environmental Adaptability and Stability
A significant advantage of PBTCA is its excellent environmental adaptability. It maintains stable corrosion inhibition across a broad pH range (6-9), making it suitable for diverse industrial water systems. Additionally, it exhibits excellent thermal stability, resisting rapid degradation even at elevated temperatures.
Compared to traditional inhibitors like chromates, PBTCA is more environmentally friendly, producing no toxic byproducts. This characteristic enhances its application value amid increasingly stringent environmental regulations.
5. Application Recommendations and Maintenance Key Points
In practical applications, it is recommended to first perform system cleaning and pre-filming treatment to establish a complete protective film. During normal operation, the dosage concentration is typically maintained at 10-20 mg/L, with specific levels determined based on water quality conditions and system characteristics.
Regular monitoring of corrosion rates is crucial for ensuring effective corrosion inhibition. This can be assessed through coupon testing or online monitoring equipment. Should an abnormal increase in corrosion rate be detected, the treatment regimen should be promptly adjusted.
Maintenance during system shutdowns is equally important. Wet preservation or dry preservation methods are recommended to prevent corrosion during inactivity. For systems undergoing long-term shutdowns, higher concentrations of corrosion inhibitors may be considered for protection.